WebTryptoquialanine (Figure 6) is a quinazoline-containing indole alkaloid produced by P. aethiopicum. It is structurally similar to a known tremorgenic mycotoxin from A. clavatus tryptoquivaline. Due to the presence of the non-proteinogenic aa anthranilic acid in the scaffold of the peptide, it was inferred that the compound is assembled by a NRPS ( Ames … WebFeb 9, 2024 · Our results reveal a novel phytopathogenic role of P. digitatum EVs and tryptoquialanine A, implying that this alkaloid is exported in EVs during plant infection. …
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WebDec 3, 2024 · The biological role of tryptoquialanines was investigated and tryptoquialanine A was submitted to insecticidal bioassays that revealed its high toxicity against Aedes … WebMar 9, 2016 · Fungal indole alkaloid biosynthesis: genetic and biochemical investigation of the tryptoquialanine pathway in Penicillium aethiopicum. J. Am. Chem. Soc. 133, 2729–2741 (2011). simple haircuts for women over 60
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WebFeb 9, 2024 · Tryptoquialanine A is a component of P. digitatum EVs. The metabolite composition of the P. digitatum EVs was investigated by UHPLC-MS/MS in EV extracts obtained in vivo (Fig. S2 and S3), followed by molecular networking in the Global Natural Products Social Molecular Networking ... WebDownload scientific diagram Tryptoquialanine A (TA) is an efficient inhibitor of germination in C. sinensis seeds. (A) Untreated seeds (negative control) showed a regular pattern of germination ... WebDec 15, 2024 · The selectivity of the method was evaluated by analyzing blank samples in comparison to spiked samples at 10 µg kg −1 to epicarp, mesocarp, and endocarp. No … rawlings youth softball pants